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March, R. E. and Hughes, R. , Quadrupole Storage Mass Spectrometry, John Wiley & Sons, New York, 1989. 42. McLuckey, S. , Van Berkel, G. , Goeringer, D. , and Glish, G. , Ion trap mass spectrometry of externally generated ions, Anal. , 66, 689A, 1994. 43. Louris, J. , Brodbelt-Lustig, J. , Cooks, R. , Glish, G. , Van Berkel, G. , and McLuckey, S. , Ion isolation and sequential stages of mass spectrometry in a quadrupole ion trap mass spectrometer, Int. J. Mass Spectrom. Ion Processes, 96, 117, 1990.

As a packet, closer to the receiver plates (cf. 24), inducing image currents onto them which are amplified and 3,7 measured. To obtain a mass spectrum over the desired m/z interval, all ions within this interval are excited simultaneously by a rapid frequency sweep of the voltage on the transmitter plates. The excitation pulse increases the orbital radii of all ions and puts ions of the same m/z ratio in phase. 25). Fourier-transformation of this timedomain signal furnishes the individual cyclotron frequencies and, hence, the m/z values (Eq.

Mass spectrometry of involatile and thermally unstable molecules, Acc. Chem. , 12, 359, 1979. 11. Udseth, H. R. , The analysis of styrene polymers by mass spectrometry with filament-heated evaporation, Anal. , 53, 29, 1981. 12. , Use of field desorption mass spectra of polystyrene and polypropylene glycol as mass references up to mass 10 000, Anal. , 51, 1329, 1979. ©2002 CRC Press LLC 13. Lattimer, R. , Harmon, D. , and Hansen, G. , Determination of molecular weight distributions of polystyrene oligomers by field desorption mass spectrometry, Anal.

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